Microsoft provides some demo or testing pages, in which the Microsoft Windows Defender SmartScreen functionality can be tested, similar to the EICAR test virus:
https://demo.smartscreen.msft.net/
Microsoft Smartscreen Test URL Rep Demos
Is This Phishing?
Alert the user to a suspicious page and ask for feedback → https://nav.smartscreen.msft.net/other/areyousure.html
Phishing Page
A page known for phishing that should be blocked → https://nav.smartscreen.msft.net/phishingdemo.html
Malware Page
A page that hosts malware and should be blocked → https://nav.smartscreen.msft.net/other/malware.html
Blocked Download
Blocked from downloading because of its URL rep → https://nav.smartscreen.msft.net/download/malwaredemo/freevideo.exe
Potentially Unwanted Download
A download that may have unwanted content → https://nav.smartscreen.msft.net/download/puaademo/freevideo.exe
This feature is available only on the next major version of Microsoft Edge, based on Chromium
Exploit Page
A page that attacks a browser vulnerability → https://demo.smartscreen.msft.net/other/exploit.html
Malvertising
A benign page hosting a malicious advertisement → https://demo.smartscreen.msft.net/other/exploit_frame.html
Microsoft Smartscreen Test App Rep Demos
Download and run these files to see how SmartScreen responds.
Known Good Program
This program should run → https://demo.smartscreen.msft.net/download/known/freevideo.exe
Unknown Program
SmartScreen should show a warning before running → https://demo.smartscreen.msft.net/download/unknown/freevideo.exe
Known Malware
SmartScreen should block this program from running → https://demo.smartscreen.msft.net/download/known/knownmalicious.exe